Atomic layer deposition of thin-film ceramic electrolytes for high-performance fuel cells

Joon Hyung Shim; Sangkyun Kang; Suk-Won Cha; Wonyoung Lee; Young Beom Kim; Joong Sun Park; Turgut M. Gür; Fritz B. Prinz; Cheng-Chieh Chao; Jihwan An

doi:10.1039/C3TA11399J

Atomic layer deposition of thin-film ceramic electrolytes for high-performance fuel cells

Joon Hyung Shim,*^a Sangkyun Kang,^b Suk-Won Cha,^c Wonyoung Lee,^d Young Beom Kim,^e Joong Sun Park,^f Turgut M. Gür,^g Fritz B. Prinz,*^gh Cheng-Chieh Chao^h and Jihwan An^h

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* Corresponding authors

^a Department of Mechanical Engineering, Korea University, Anam-dong, Seongbuk-gu, Seoul 136-713, Korea
E-mail: shimm@korea.ac.kr
Fax: +82 2-926-9290
Tel: +82 2-3290-3353

^b Hanchang Ind. Co., Ltd., 566-4 Yodang-ri, Yanggam-myeon, Hwasung-si, Gyeonggi-do, Korea

^c School of Mechanical and Aerospace Engineering, Seoul National University, San 56-1, Shilim-dong, Kwanak-gu, Seoul, Korea

^d School of Mechanical Engineering, Sungkyunkwan University, 300 Cheoncheon-dong, Suwon, Gyeonggi-do 440-746, Korea

^e Department of Mechanical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul, Korea

^f Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

^g Department of Mechanical Engineering, Stanford University, Stanford, CA 94305, USA
E-mail: fbp@cdr.stanford.edu
Fax: +1 650-725-4862
Tel: +1 650-723-4023

^h Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA

Abstract

This feature article provides a progress review of atomic layer deposition (ALD) for fabrication of oxide-ion as well as proton conducting ceramic fuel cells. A comprehensive analysis of structural, chemical, surface kinetics, and electrochemical characterization results of ALD membranes is also presented. ALD is a surface reaction limited method of depositing conformal, high quality, pinhole-free, uniform thickness nanofilms onto planar or three-dimensional structures. Deposition by one atomic layer at a time also affords unprecedented opportunities to engineer surface termination, to form compositionally graded structures or graded doping, and to synthesize metastable phases that cannot be realized otherwise. Indeed, thin ceramic electrolyte membranes made by ALD exhibit enhanced surface exchange kinetics, reduced ohmic losses, and superior fuel cell performance as high as 1.34 W cm⁻² at 500 °C. More importantly, ALD offers the opportunity to design and engineer surface structures at the atomic scale targeting improved performance of not only ceramic fuel cells, but also electrochemical sensors, electrolysers and pumps.

Journal of Materials Chemistry A

Atomic layer deposition of thin-film ceramic electrolytes for high-performance fuel cells

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Atomic layer deposition of thin-film ceramic electrolytes for high-performance fuel cells

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